A New Method for Simultaneous Measurement of Cl−, Br−, NO3−, SCN−, and I− at Sub-ppm Levels in Ground Water

ABSTRACT Ion‐exchange high performance liquid chromatography coupled with ultraviolet absorption detection is shown to be a rapid and sensitive method for analysis of some common anions in water. Sensitivity of measurement is approximately 50 ppb for NO−2, NO−3, Br−, I−, and SCN− while Cl− has a detection limit in the one to ten ppm range. Chromatograms require 8 to 13 minutes to complete. Analyses are performed on either of two stationary phases (Whatman SAX 10 μm or Brownlee anion exchange) depending on the anions of interest in the analysis and their interferences.