Recovery of high-concentration volatile fatty acids from wastewater using an acidogenesis-electrodialysis integrated system

[Display omitted] •VFAs were effectively recovered from wastewater fermentation broth by ED.•The ED-acidogenic reactor allowed continuous in-situ recovery of VFAs.•Significant up-concentration of acetate, propionate and butyrate was achieved.•Net migration rate declined in the later stage due to VFAs over-accumulation. Recovery of volatile fatty acids (VFAs) from wastewater is an important route for wastewater valorization. Selective acidogenic fermentation enables an efficient production of VFAs from wastewater, whereas electrodialysis (ED) provides an effective approach to concentrate VFAs. However, these two processes have not been coupled in one single system previously. In this study, an acidogenesis-ED integrated system that coupled a continuous acidogenesis with a batch process of VFA concentration was developed for recovery of high-concentration VFAs from wastewater. Under 20.0 V voltage, the acetate was concentrated by 4-fold and the propionate and butyrate were concentrated by over 3-fold in the integrated system after 528-h operation. The declined VFAs recovery ratios at the later stage due to significant reverse diffusion indicate a need to prevent product over-accumulation. This work demonstrated the feasibility of the acidogenesis-ED integrated reactor for wastewater valorization and discussed the remaining challenges and opportunities.