Synthesis and characterization of series of promising decontaminants for organophosphorus compounds
A novel 6,7-epoxy, N N', N'-trichloro-t-cinnamaldehyde semicarbazone has been synthesized, by conversion of t-cinnamaldehyde into its very stable semicarbazone derivative, followed by both epoxidation and N-chlorination (electrophilic) respectively. Calcium hypochlorite was the source of e...
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Veröffentlicht in: | Oriental journal of chemistry 2008-12, Vol.24 (3), p.1131-1134 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A novel 6,7-epoxy, N N', N'-trichloro-t-cinnamaldehyde semicarbazone has been synthesized, by conversion of t-cinnamaldehyde into its very stable semicarbazone derivative, followed by both epoxidation and N-chlorination (electrophilic) respectively. Calcium hypochlorite was the source of electrophilic chlorine. The physical characterization is reported and achieved for each member of the series by mass, FT-IR and super(1)H NMR studies. Both the epoxide as well as the trichoro-derivatjves are expected to act as suitable and efficient decontaminants for the toxic organophosphorus (C-O-P and C-N-P) compounds due to their functions as the oxidizing agents mainly. |
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ISSN: | 0970-020X |