Remote Control over Underwater Dynamic Attachment/Detachment and Locomotion

Despite extensive efforts to mimic the fascinating adhesion capability of geckos, the development of reversible adhesives underwater has long been lagging. The appearance of mussels‐inspired dopamine chemistry has provided the feasibility to fabricate underwater adhesives; however, for such a system, imitating the reversible and fast dynamic attachment/detachment mechanism of gecko feet still remains unsolved. Here, by synthesizing a thermoresponsive copolymer of poly(dopamine methacrylamide‐co‐methoxyethyl‐acrylate‐co‐N‐isopropyl acrylamide) and then decorating it onto mushroom‐shaped poly(dimethylsiloxane) pillar arrays, a novel underwater thermoresponsive gecko‐like adhesive (TRGA) can be fabricated, yielding high adhesion during the attachment state above the lower critical solution temperature (LCST) of the copolymer, yet low adhesion during the detachment state below the LCST of the copolymer. By integrating the Fe3O4 nanoparticles into the TRGA, TRGAs responsive to near‐infrared laser radiation can be engineered, which can be successfully used for rapid and reversible remote control over adhesion so as to capture and release heavy objects underwater because of the contrast force change of both the normal adhesion force and the lateral friction force. It is also demonstrated that the material can be assembled on the tracks of an underwater mobile device to realize controllable movement. This opens up the door for developing intelligent underwater gecko‐like locomotion with dynamic attachment/detachment ability. A kind of intelligent underwater thermoresponsive gecko adhesive (TRGA) with switchable adhesion feature is prepared in response to temperature change triggered by external near‐infrared light. The TRGA can exhibit low adhesion/friction force against contact surfaces at low temperature, but high adhesion/friction force at high temperature underwater along with excellent reversibility, which enables successful manufacture of mobile robots underwater/or in wet conditions.