Mechanisms of the H2- and transfer hydrogenation of polar bonds catalyzed by iron group hydrides

Mechanisms of the H2- and transfer hydrogenation of polar bonds catalyzed by iron group hydrides

This perspective reviews our efforts to use a mechanism-based approach to develop catalysts for the asymmetric hydrogenation of prochiral ketones and imines. A goal is to discover catalysts based on the abundant 3d transition metals, particularly iron.

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Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (32), p.10809-10826
1. Verfasser: Morris, Robert H
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Hydrogenation
Imines
Iron
Ketones
Transition metals
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Beschreibung
Zusammenfassung:This perspective reviews our efforts to use a mechanism-based approach to develop catalysts for the asymmetric hydrogenation of prochiral ketones and imines. A goal is to discover catalysts based on the abundant 3d transition metals, particularly iron.
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt01804a