Photo-Induced Aziridination of Alkenes with N-Sulfonyliminoiodinanes

Photo-Induced Aziridination of Alkenes with N-Sulfonyliminoiodinanes

Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375 nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mechanism via radical intermediates rather than...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 2018/06/01, Vol.66(6), pp.688-690
Hauptverfasser: Masakado, Sota, Kobayashi, Yusuke, Takemoto, Yoshiji
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
aziridination
Chemical reactions
hypervalent iodine
iminoiodinane
Intermediates
Irradiation
photoreaction
Radiation
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Zusammenfassung:Activation of N-sulfonyliminiodinanes was achieved by photo-irradiation at 375 nm, which enabled the reaction with several alkenes to afford the corresponding aziridines. Mechanistic studies suggested that the reaction would proceed through a stepwise mechanism via radical intermediates rather than through a concerted process.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.c18-00198