Two dominant self-assembly pathways to a Pd3L6 double-walled triangle

Two dominant self-assembly pathways to a Pd3L6 double-walled triangle

An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (56), p.7758-7761
Hauptverfasser: Tateishi, Tomoki, Shumpei Kai, Sasaki, Yuya, Kojima, Tatsuo, Takahashi, Satoshi, Hiraoka, Shuichi
Format: Artikel
Sprache:eng
Schlagworte:
NMR
Nuclear magnetic resonance
Quantitative analysis
Self-assembly
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the intramolecular macrocyclization and the formation of double-walls took place leading to the final assembly.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc02608d