Synthesis and Characterization of Stable Phosphorus Carbabetaines

Phosphorus 1,3‐ and 1,4‐carbabetaines with ′P(+)−C−C(−)′ and ′P(+)−C−C−C(−)′ structures, respectively, in which the carbanion moiety was significantly stabilized by two trifluoromethylsulfonyl groups, have been synthesized and characterized. Analysis of their X‐ray crystal structures revealed that any attractive interactions between the anionic and cationic moieties were negligibly weak. This result was corroborated by using natural bond orbital (NBO) and Bader′s quantum theory of atoms in molecules (QTAIM) models. In contrast, performing the same analysis of a known 1,3‐carbabetaine equivalent, which can be drawn as a ′P(+)−C−C=C−O(−)′ resonance structure, revealed pronounced charge‐transfer interactions between the anionic and cationic moieties. Carba loading: Experimental and theoretical analysis of adducts that were formed from the reaction of 1,1‐bis(trifluoromethylsulfonyl)ethylene (Tf2C=CH2) with phosphorus‐containing nucleophiles revealed the presence of negligibly weak interactions between the anionic and cationic moieties. These adducts are the first examples of pronounced phosphorus carbabetaines with a ′C(−)−(C)n−P(+)′ structure (n=1, 2).