Photoredox Reactions of Quinones

Photoredox reactions of quinones are reviewed, that enable C−H bond oxidation at the vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under photoirradiation. Mechanistic insights on the benzo‐, naphtho‐, and anthraquinones are discussed. Also the potential utilities...

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Veröffentlicht in:Chemistry : a European journal 2018-10, Vol.24 (60), p.15955-15964
Hauptverfasser: Ando, Yoshio, Suzuki, Keisuke
Format: Artikel
Sprache:eng
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Zusammenfassung:Photoredox reactions of quinones are reviewed, that enable C−H bond oxidation at the vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under photoirradiation. Mechanistic insights on the benzo‐, naphtho‐, and anthraquinones are discussed. Also the potential utilities in organic synthesis are described. Photoredox reactions of quinones are reviewed, that enable C−H bond oxidation at the vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under photoirradiation. Mechanistic insights on the benzo‐, naphtho‐, and anthraquinones are discussed. Also, the potential utilities in organic synthesis are described.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201801064