Molecular Paneling by Coordination: An M15 L6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion

Molecular Paneling by Coordination: An M15 L6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion

Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [PdII (en)] (en=ethylenediamine) into a unique M15 L6 hexahedral coordination capsule (see X-ray structure). The capsule can...

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Veröffentlicht in:Angewandte Chemie International Edition 2001-07, Vol.40 (14), p.2620-2622
Hauptverfasser: Umemoto, Kazuhiko, Tsukui, Hitoshi, Kusukawa, Takahiro, Biradha, Kumar, Fujita, Makoto
Format: Artikel
Sprache:eng
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Zusammenfassung:Only one positional isomer is obtained from the assembly of 21 small components. A triangular molecular panel with five coordination sites is assembled upon complexation with [PdII (en)] (en=ethylenediamine) into a unique M15 L6 hexahedral coordination capsule (see X-ray structure). The capsule can encapsulate/exchange organic guests reversibly through the clefts at the nonbinding sites of the capsule.
ISSN:1521-3773
DOI:10.1002/1521-3773(20010716)40:14<2620::AID-ANIE2620>3.0.CO;2-E