Supramolecular Chemistry of Anionic Cobalt(III) Bis(dicarbollide) and Cyclotriveratrylene in the Solid State and the Gas Phase

Supramolecular Chemistry of Anionic Cobalt(III) Bis(dicarbollide) and Cyclotriveratrylene in the Solid State and the Gas Phase

Polymer layers templated around [Co(C2B9H11)2]− (1) counter ions are one of the structural features of the two‐dimensional coordination polymer obtained in crystalline form from Na‐1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Nan(CTV)m...

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Veröffentlicht in:Angewandte Chemie International Edition 2000-11, Vol.39 (21), p.3835-3839
Hauptverfasser: Hardie, Michaele J., Raston, Colin L.
Format: Artikel
Sprache:eng
Schlagworte:
carboranes
cobalt
cyclotriveratrylene
host-guest chemistry
supramolecular chemistry
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Zusammenfassung:Polymer layers templated around [Co(C2B9H11)2]− (1) counter ions are one of the structural features of the two‐dimensional coordination polymer obtained in crystalline form from Na‐1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Nan(CTV)m]n+ clusters are present in the gas phase and can complex one or two [Co(C2B9H11)]− ions.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-Q