Cyclic Hexamer with a Cubic Cavity: Crystal Structure of [{Rh(6-Purinethione Ribosido)(Cp)}6](CF3SO3)6

Cyclic Hexamer with a Cubic Cavity: Crystal Structure of [{Rh(6-Purinethione Ribosido)(Cp)}6](CF3SO3)6

The stereoselective formation of a pseudo‐S6 hexamer resulted from the self‐assembling reaction between [Rh(Cp*)(H2O)3]2+ and 6‐purinethione riboside (see left structure; Cp*=C5Me5). The schematic representation (right) shows the direction of the coordination to the S6 and N(7) donor atoms. C (clock...

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Veröffentlicht in:Angewandte Chemie International Edition 2001-06, Vol.40 (12), p.2268-2271
Hauptverfasser: Yamanari, Kazuaki, Yamamoto, Shiori, Ito, Rie, Kushi, Yoshihiko, Fuyuhiro, Akira, Kubota, Naoko, Fukuo, Tsuyoshi, Arakawa, Ryuichi
Format: Artikel
Sprache:eng
Schlagworte:
chirality
nucleosides
rhodium
self-assembly
supramolecular chemistry
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Beschreibung
Zusammenfassung:The stereoselective formation of a pseudo‐S6 hexamer resulted from the self‐assembling reaction between [Rh(Cp*)(H2O)3]2+ and 6‐purinethione riboside (see left structure; Cp*=C5Me5). The schematic representation (right) shows the direction of the coordination to the S6 and N(7) donor atoms. C (clockwise) and A (anticlockwise) indicate the chirality of each unit complex.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20010618)40:12<2268::AID-ANIE2268>3.0.CO;2-K