Higher Adducts of C60 by Tether-Directed Remote Functionalization: X-Ray Crystal Structure and Reactivity of a Chiral Hexakis-Cyclopropanated Fullerene with all Addends Located along an Equatorial Belt

Higher Adducts of C60 by Tether-Directed Remote Functionalization: X-Ray Crystal Structure and Reactivity of a Chiral Hexakis-Cyclopropanated Fullerene with all Addends Located along an Equatorial Belt

An unprecedented addition pattern for the novel hexakis‐cyclopropanated C60 (±)‐1 was prepared by a sequence of tether‐directed regioselective remote functionalizations. The X‐ray crystal structure revealed the positioning of the six addends in a distinct helical array along an equatorial belt....

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Veröffentlicht in:Angewandte Chemie International Edition 2000-11, Vol.39 (21), p.3813-3816
Hauptverfasser: Woods, Craig R., Bourgeois, Jean-Pascal, Seiler, Paul, Diederich, François
Format: Artikel
Sprache:eng
Schlagworte:
conjugation
fullerenes
regioselectivity
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Zusammenfassung:An unprecedented addition pattern for the novel hexakis‐cyclopropanated C60 (±)‐1 was prepared by a sequence of tether‐directed regioselective remote functionalizations. The X‐ray crystal structure revealed the positioning of the six addends in a distinct helical array along an equatorial belt.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20001103)39:21<3813::AID-ANIE3813>3.0.CO;2-5