Solid-Phase Immobilization of a New Epoxidation Catalyst

Solid-Phase Immobilization of a New Epoxidation Catalyst

The heterogenization of a titanium(IV) silsesquioxane complex in an MCM‐41 molecular sieve, by tailoring the polarity of MCM‐41, results in self‐assembled materials (see the space‐filling model on the right) that are active, truly heterogeneous, and recyclable catalysts for liquid‐phase alkene epoxi...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-02, Vol.37 (3), p.356-358
Hauptverfasser: Krijnen, Simon, Abbenhuis, Hendrikus C. L., Hanssen, Rob W. J. M., van Hooff, Jan H. C., van Santen, Rutger A.
Format: Artikel
Sprache:eng
Schlagworte:
Epoxidations
Heterogeneous catalysis
Immobilization
Titanium
Zeolites
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Beschreibung
Zusammenfassung:The heterogenization of a titanium(IV) silsesquioxane complex in an MCM‐41 molecular sieve, by tailoring the polarity of MCM‐41, results in self‐assembled materials (see the space‐filling model on the right) that are active, truly heterogeneous, and recyclable catalysts for liquid‐phase alkene epoxidation.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19980216)37:3<356::AID-ANIE356>3.0.CO;2-5