Solid-Phase Synthesis and Encoding Strategies for Olefin Polymerization Catalyst Libraries

Solid-Phase Synthesis and Encoding Strategies for Olefin Polymerization Catalyst Libraries

Active polymerization catalysts, novel resin‐bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer‐coat...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-12, Vol.37 (23), p.3272-3275
Hauptverfasser: Boussie, Thomas R., Coutard, Carla, Turner, Howard, Murphy, Vince, Powers, Timothy S.
Format: Artikel
Sprache:eng
Schlagworte:
Combinatorial chemistry
Heterogeneous catalysis
Polymers
Solid-phase synthesis
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Zusammenfassung:Active polymerization catalysts, novel resin‐bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis and combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage of the tag from the polymer‐coated resin, HPLC can be used to determine the pathway along which the products were formed.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19981217)37:23<3272::AID-ANIE3272>3.0.CO;2-R