Remarkable Reaction of Hetero-S-Block-Metal Amides with Molecular Oxygen: Cationic (NMNMg)2 Ring Products (M=Li or Na) with Anionic Oxo or Peroxo Cores

Remarkable Reaction of Hetero-S-Block-Metal Amides with Molecular Oxygen: Cationic (NMNMg)2 Ring Products (M=Li or Na) with Anionic Oxo or Peroxo Cores

Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium‐substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-12, Vol.37 (22), p.3180-3183
Hauptverfasser: Kennedy, Alan R., Mulvey, Robert E., Rowlings, René B.
Format: Artikel
Sprache:eng
Schlagworte:
Alkali metals
Amides
Heterodimetallic compounds
Oxygenations
Structure elucidation
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Beschreibung
Zusammenfassung:Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium‐substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D