The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters

The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters

A long‐standing challenge to synthesis can now be met through the use of new and powerful catalytic asymmetric reactions for the assembly of complex chiral molecules with quaternary stereocenters from achiral building blocks. The reaction sequence shown below is just one example discussed in this re...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-03, Vol.37 (4), p.388-401
Hauptverfasser: Corey, Elias J., Guzman-Perez, Angel
Format: Artikel
Sprache:eng
Schlagworte:
Asymmetric catalysis
Chirality
Enantioselective addition
Quaternary stereocenters
Total synthesis
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Zusammenfassung:A long‐standing challenge to synthesis can now be met through the use of new and powerful catalytic asymmetric reactions for the assembly of complex chiral molecules with quaternary stereocenters from achiral building blocks. The reaction sequence shown below is just one example discussed in this review.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19980302)37:4<388::AID-ANIE388>3.0.CO;2-V