Synthesis and Structural Analysis of a Helical Coordination Polymer Formed by the Self-Assembly of a 2,2′-Bipyridine-Based exo-Ditopic Macrocyclic Ligand and Silver Cations

Synthesis and Structural Analysis of a Helical Coordination Polymer Formed by the Self-Assembly of a 2,2′-Bipyridine-Based exo-Ditopic Macrocyclic Ligand and Silver Cations

The overall topology of coordination polymers can be controlled by means of the coordination preferences of the metal center and the structure of the bridging ligand. This is demonstrated here by the synthesis of a single‐stranded helical coordination polymer by the self‐assembly of the exo‐ditopic...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-04, Vol.37 (7), p.920-922
Hauptverfasser: Kaes, Christian, Hosseini, Mir Wais, Rickard, Clifton E. F., Skelton, Brian W., White, Allan H.
Format: Artikel
Sprache:eng
Schlagworte:
Coordination polymers
Helical structures
N ligands
Self-assembly
Silver
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Zusammenfassung:The overall topology of coordination polymers can be controlled by means of the coordination preferences of the metal center and the structure of the bridging ligand. This is demonstrated here by the synthesis of a single‐stranded helical coordination polymer by the self‐assembly of the exo‐ditopic ligand 1 and silver ions.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19980420)37:7<920::AID-ANIE920>3.0.CO;2-O