Molecular Topology: Easy Self-Assembly of an Organometallic Doubly Braided [2]Catenane

Molecular Topology: Easy Self-Assembly of an Organometallic Doubly Braided [2]Catenane

Molecular tailoring through the judicious choice of hinge group has enabled the synthesis of a family of topologically related structures, among which is the first structurally characterized doubly braided catenane (see picture), a compound that undergoes an easy molecular switching motion.

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Veröffentlicht in:Angewandte Chemie International Edition 2000-11, Vol.39 (21), p.3819-3822
Hauptverfasser: McArdle, Christopher P., Vittal, Jagadese J., Puddephatt, Richard J.
Format: Artikel
Sprache:eng
Schlagworte:
aurophilicity
catenanes
gold
macrocycles
supramolecular chemistry
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Beschreibung
Zusammenfassung:Molecular tailoring through the judicious choice of hinge group has enabled the synthesis of a family of topologically related structures, among which is the first structurally characterized doubly braided catenane (see picture), a compound that undergoes an easy molecular switching motion.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20001103)39:21<3819::AID-ANIE3819>3.0.CO;2-6