A Functionalized Heterocubane with Extensive Intermolecular Hydrogen Bonds

A Functionalized Heterocubane with Extensive Intermolecular Hydrogen Bonds

A unique three‐dimensional assembly is evident in the crystal structure of the cage compound 1: each molecule participates in the formation of eight O−H⋅⋅⋅O hydrogen bonds with neighboring molecules to form cavities with approximate dimensions of 3×3×8 Å3. In contrast, compound 2, which contains the...

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Veröffentlicht in:Angewandte Chemie International Edition 1999-03, Vol.38 (5), p.661-664
Hauptverfasser: Said, Musa A., Roesky, Herbert W., Rennekamp, Carsten, Andruh, Marius, Schmidt, Hans-Georg, Noltemeyer, Mathias
Format: Artikel
Sprache:eng
Schlagworte:
Cage compounds
Hydrogen bonds
Silicon
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Zusammenfassung:A unique three‐dimensional assembly is evident in the crystal structure of the cage compound 1: each molecule participates in the formation of eight O−H⋅⋅⋅O hydrogen bonds with neighboring molecules to form cavities with approximate dimensions of 3×3×8 Å3. In contrast, compound 2, which contains the same framework structure, does not show this behavior in the crystal.
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19990301)38:5<661::AID-ANIE661>3.0.CO;2-G