A cyano-bridged Cu(i)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe3+ ions

A cyano-bridged Cu(i)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe3+ ions

A cyano-bridged Cu(i) organic framework based on [Cu6(CN)6]n was synthesized, in which cyano anions were generated in situ from the C–C bond cleavage of acetonitrile. The as-synthesized compound displays orange-red luminescence and is further proven to be a promising Fe3+ luminescent sensor with hig...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2018-05, Vol.47 (20), p.6888-6892
Hauptverfasser: Gai, Yanli, Zhao, Xueyan, Chen, Yan, Yang, Silei, Xia, Xinshu, Liu, Shan, Wan, Xiuyan, Xiong, Kecai
Format: Artikel
Sprache:eng
Schlagworte:
Acetonitrile
Cleavage
Synthesis
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Zusammenfassung:A cyano-bridged Cu(i) organic framework based on [Cu6(CN)6]n was synthesized, in which cyano anions were generated in situ from the C–C bond cleavage of acetonitrile. The as-synthesized compound displays orange-red luminescence and is further proven to be a promising Fe3+ luminescent sensor with high selectivity and sensitivity.
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt00979a