Design of task-specific fluorinated ionic liquids: nanosegregation versus hydrogen-bonding ability in aqueous solutions

Design of task-specific fluorinated ionic liquids: nanosegregation versus hydrogen-bonding ability in aqueous solutions

We demonstrate that fluorinated ionic liquids reduce the impact of the addition of water upon the ionic liquid's H-bond acceptance ability. This is a key factor to obtain functionalized materials to be used e.g. in the dissolution of biomolecules, extraction processes or material engineering.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018-04, Vol.54 (28), p.3524-3527
Hauptverfasser: Bastos, Joana C, Carvalho, Sara F, Welton, Tom, Canongia Lopes, José N, Rebelo, Luís Paulo N, Shimizu, Karina, Araújo, João M M, Pereiro, Ana B
Format: Artikel
Sprache:eng
Schlagworte:
Biomolecules
Chemical bonds
Fluorination
Hydrogen bonding
Ionic liquids
Ions
Solvents
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Zusammenfassung:We demonstrate that fluorinated ionic liquids reduce the impact of the addition of water upon the ionic liquid's H-bond acceptance ability. This is a key factor to obtain functionalized materials to be used e.g. in the dissolution of biomolecules, extraction processes or material engineering.
ISSN:1359-7345
1364-548X
DOI:10.1039/C8CC00361K