FATE AND KINETICS OF CARFENTRAZONE-ETHYL HERBICIDE IN CALIFORNIA, USA, FLOODED RICE FIELDS

Little is known of the environmental fate of the aryltriazolinone herbicide carfentrazone-ethyl (compound I). Rice field applications of Shark[reg.] 40D commercial formulation to duplicate 5.7 m super(2) rings (119 g a.i./ha) and 464 m super(2) commercial basins (224 g a.i./ha) produced pseudo-first-order half-lives (t sub(1/2)) of 6.5 to 11.1 h in water and 37.9 to 174 h in sediment. The rapid dissipation from water was due to its hydrolysis to the chloropropionic acid (compound II), which further degraded to its propionic, cinnamic, and benzoic acids. Compound I degraded similarly in soil, but propionic and cinnamic acid levels were higher. Compound I was only weakly adsorbed, but lateral movement of compound II through soil occurred. Laboratory hydrolysis produced quantitative yields of compound II, t sub(1/2) values of 131 h at pH 7 and 3.36 h at pH 9, and slow dissipation at pH 5 (43% at 830 h). Ultraviolet (UV) irradiation of compound I in pH 7 buffer gave dissipation rates similar to those in dark controls (t sub(1/2) 113 h vs 128 h), while compound II was comparatively stable to photolysis (t sub(1/2) 765 h) and also did not volatilize from water. Ester hydrolysis followed by off-site movement of the acid (compound II) account for the dissipation of compound I.