Lowering greening of cookies made from sunflower butter using acidic ingredients and effect on reducing capacity, tryptophan and protein oxidation

•Use of acidic ingredients decreased greening in cookies made with sunflower butter.•Greening intensity was positively correlated to pH (r = 0.77).•pH was negatively correlated with chlorogenic acid (r = −0.96).•Most green cookies had the most tryptophan quenching.•Greening reaction did not negative...

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Veröffentlicht in:Food chemistry 2018-06, Vol.252, p.318-326
Hauptverfasser: Liang, Sihui, Tran, Hanh Lan, Were, Lilian
Format: Artikel
Sprache:eng
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Zusammenfassung:•Use of acidic ingredients decreased greening in cookies made with sunflower butter.•Greening intensity was positively correlated to pH (r = 0.77).•pH was negatively correlated with chlorogenic acid (r = −0.96).•Most green cookies had the most tryptophan quenching.•Greening reaction did not negatively affect antioxidant capacity. Lowering of greening formed from oxidized chlorogenic acid (CGA) and amino groups, and favoured at alkaline pH, was investigated using acidic ingredients (sour cream, buttermilk, yoghurt, and honey) in sunflower butter cookies. Cookies with maple syrup added were used as a positive control. Changes in greening intensity, greening reactants (total phenols, CGA, protein), antioxidant capacity, tryptophan and Schiff base fluorescence were measured. Percentage greening, pH and aw of cookies followed the same order: maple syrup > sour cream ≥ buttermilk > yoghurt > honey. pH was positively correlated with greening intensity (r = 0.77) and negatively correlated with CGA (r = −0.96). Total phenolic content, antioxidant capacity, tryptophan and Schiff bases were similar among cookies. The results suggest it is possible to decrease greening by minimizing storage time and using acidic ingredients. Minimal greening with acidic ingredients can extend the application of sunflower butter as a baking ingredient without loss of free radical-scavenging capacity, or higher protein oxidation.
ISSN:0308-8146
1873-7072
DOI:10.1016/j.foodchem.2018.01.118