Enhancement of metal-metal interactions inside a large-cavity synthetic host in water

Enhancement of metal-metal interactions inside a large-cavity synthetic host in water

The encapsulation of a series of metal-terpyridyl complexes in cucurbit[10]uril (CB[10]) in water is described. A strong enhancement of metal-metal and π-π interactions is observed due to double confinement in the large cavity. Furthermore, a linear supramolecular polymer featuring host-enhanced met...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (17), p.2169-2172
Hauptverfasser: Kuang, Shengjian, Hu, Zhixiong, Zhang, Hao, Zhang, Xiongzhi, Liang, Feng, Zhao, Zhiyong, Liu, Simin
Format: Artikel
Sprache:eng
Schlagworte:
Coordination compounds
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Zusammenfassung:The encapsulation of a series of metal-terpyridyl complexes in cucurbit[10]uril (CB[10]) in water is described. A strong enhancement of metal-metal and π-π interactions is observed due to double confinement in the large cavity. Furthermore, a linear supramolecular polymer featuring host-enhanced metallophilic interactions in water can be prepared.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc00593a