Near-infrared electrochemiluminescence from orange fluorescent Au nanoclusters in water

We report the unusual generation of near-infrared (near-IR) electrochemiluminescence (ECL) from water-soluble Au nanoclusters (NCs), of which the photoluminescence is primarily within the visible wavelength region. The near-IR ECL is ascribed to the Au(0)-glutathione motif in the Au NCs stabilized b...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (23), p.2838-2841
Hauptverfasser: Kim, Jun Myung, Jeong, Seonghyun, Song, Jae Kyu, Kim, Joohoon
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Sprache:eng
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Zusammenfassung:We report the unusual generation of near-infrared (near-IR) electrochemiluminescence (ECL) from water-soluble Au nanoclusters (NCs), of which the photoluminescence is primarily within the visible wavelength region. The near-IR ECL is ascribed to the Au(0)-glutathione motif in the Au NCs stabilized by glutathione in water. We report the unusual generation of near-IR electrochemiluminescence from orange fluorescent Au nanoclusters soluble in water.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc09394b