Palladium‐Catalyzed C−H Silylation through Palladacycles Generated from Aryl Halides

A highly efficient palladium‐catalyzed disilylation reaction of aryl halides through C−H activation has been developed for the first time. The reaction has broad substrate scope. A variety of aryl halides can be disilylated by three types of C−H activation, including C(sp2)−H, C(sp3)−H, and remote C...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2018-03, Vol.57 (12), p.3233-3237
Hauptverfasser:	Lu, Ailan, Ji, Xiaoming, Zhou, Bo, Wu, Zhuo, Zhang, Yanghui
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Aromatic compounds biaryls C−H activation Halides palladacycles Palladium reaction mechanism Substrates
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!