Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone
The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was...
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| Veröffentlicht in: | Journal of chemical technology and biotechnology (1986) 2004-01, Vol.79 (6), p.658-662 |
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| Sprache: | eng |
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| container_end_page | 662 |
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| container_issue | 6 |
| container_start_page | 658 |
| container_title | Journal of chemical technology and biotechnology (1986) |
| container_volume | 79 |
| creator | Liang, Xinhua Mi, Zhentao Wang, Yaquan Wang, Li Zhang, Xiangwen Wu, Wei Min, Enze Fu, Songbao |
| description | The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated. |
| doi_str_mv | 10.1002/jctb.1037 |
| format | Article |
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The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated.</description><identifier>ISSN: 0268-2575</identifier><identifier>DOI: 10.1002/jctb.1037</identifier><language>eng</language><ispartof>Journal of chemical technology and biotechnology (1986), 2004-01, Vol.79 (6), p.658-662</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Liang, Xinhua</creatorcontrib><creatorcontrib>Mi, Zhentao</creatorcontrib><creatorcontrib>Wang, Yaquan</creatorcontrib><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Zhang, Xiangwen</creatorcontrib><creatorcontrib>Wu, Wei</creatorcontrib><creatorcontrib>Min, Enze</creatorcontrib><creatorcontrib>Fu, Songbao</creatorcontrib><title>Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone</title><title>Journal of chemical technology and biotechnology (1986)</title><description>The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated.</description><issn>0268-2575</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqNjjsLwjAUhTMoWB-D_yCT6KCmKX3NonTTwcGtpPH2RZpobwr139uhODt9B8534BCydtnBZYwfa2mzIXnhhDiMB9Ge-6E_I3PEmjEWRDxwyOPWGgmItNIWilbYymhqcppQ7LIt311H0gI0jLXQT2pLoKJpTF81v438SGVK6IU2GpZkmguFsBq5IJvL-X5K9q_WvDtAmzYVSlBKaDAdpm4cD_fiyPtb_AL54UgT</recordid><startdate>20040101</startdate><enddate>20040101</enddate><creator>Liang, Xinhua</creator><creator>Mi, Zhentao</creator><creator>Wang, Yaquan</creator><creator>Wang, Li</creator><creator>Zhang, Xiangwen</creator><creator>Wu, Wei</creator><creator>Min, Enze</creator><creator>Fu, Songbao</creator><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20040101</creationdate><title>Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone</title><author>Liang, Xinhua ; Mi, Zhentao ; Wang, Yaquan ; Wang, Li ; Zhang, Xiangwen ; Wu, Wei ; Min, Enze ; Fu, Songbao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_199257983</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Xinhua</creatorcontrib><creatorcontrib>Mi, Zhentao</creatorcontrib><creatorcontrib>Wang, Yaquan</creatorcontrib><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Zhang, Xiangwen</creatorcontrib><creatorcontrib>Wu, Wei</creatorcontrib><creatorcontrib>Min, Enze</creatorcontrib><creatorcontrib>Fu, Songbao</creatorcontrib><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Xinhua</au><au>Mi, Zhentao</au><au>Wang, Yaquan</au><au>Wang, Li</au><au>Zhang, Xiangwen</au><au>Wu, Wei</au><au>Min, Enze</au><au>Fu, Songbao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone</atitle><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle><date>2004-01-01</date><risdate>2004</risdate><volume>79</volume><issue>6</issue><spage>658</spage><epage>662</epage><pages>658-662</pages><issn>0268-2575</issn><abstract>The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated.</abstract><doi>10.1002/jctb.1037</doi></addata></record> |
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| identifier | ISSN: 0268-2575 |
| ispartof | Journal of chemical technology and biotechnology (1986), 2004-01, Vol.79 (6), p.658-662 |
| issn | 0268-2575 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone |
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