Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone

The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was...

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Veröffentlicht in:Journal of chemical technology and biotechnology (1986) 2004-01, Vol.79 (6), p.658-662
Hauptverfasser: Liang, Xinhua, Mi, Zhentao, Wang, Yaquan, Wang, Li, Zhang, Xiangwen, Wu, Wei, Min, Enze, Fu, Songbao
Format: Artikel
Sprache:eng
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Zusammenfassung:The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated.
ISSN:0268-2575
DOI:10.1002/jctb.1037