Process integration of H sub(2)O sub(2) generation and the ammoximation of cyclohexanone
The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was...
Gespeichert in:
Veröffentlicht in: | Journal of chemical technology and biotechnology (1986) 2004-01, Vol.79 (6), p.658-662 |
---|---|
Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The possibility of the integration of the processes of H sub(2)O sub(2) generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H sub(2)O sub(2) and NH sub(3) TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H sub(2)O sub(2) solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H sub(2)O sub(2) generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated. |
---|---|
ISSN: | 0268-2575 |
DOI: | 10.1002/jctb.1037 |