Prussian Blue‐Derived Iron Phosphide Nanoparticles in a Porous Graphene Aerogel as Efficient Electrocatalyst for Hydrogen Evolution Reaction

Tailoring of new hydrogen evolution reaction (HER) electrocatalyst with earth abundant elements is important for large scale water splitting and hydrogen production. In this work, we present a simple synthetic method for incorporating iron phosphide (FeP) particles into three‐dimensional (3D) porous graphene aerogel (GA) structure. The FeP formed in porous 3D GA (FeP/GA) is derived from electroactive Fe hexacyanoferrate (FeHCF). The advantage of incorporating FeP, in the porous 3D graphene network enables high accessibility for HER. As synthesized FeP/GA catalyst shows good electrocatalytic activity for HER in both acidic and alkaline solutions. The developed method can be useful for synthesizing metal hexacyanoferrate derived mono/bimetal phosphide catalyst in porous 3D graphene aerogels. HER achievement: The incorporation of iron phosphide (FeP) particles into a three‐dimensional (3D) porous graphene aerogel (GA) structure is reported. The FeP is derived from electroactive Fe hexacyanoferrate (FeHCF). The as‐synthesized FeP/GA catalyst shows good electrocatalytic activity for HER in both of acidic and alkaline solutions. The developed method may be of use for synthesizing metal hexacyanoferrate‐derived mono/bimetal phosphide catalysts in porous 3D graphene aerogels.