A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

We report the synthesis of manganese(iii)-peroxo (Mn (O )) and manganese(iii)-hydroperoxo (Mn (O H)) complexes by activating dioxygen (O ) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (10), p.1209-1212
Hauptverfasser: Sankaralingam, Muniyandi, Lee, Yong-Min, Jeon, So Hyun, Seo, Mi Sook, Cho, Kyung-Bin, Nam, Wonwoo
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Manganese
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Zusammenfassung:We report the synthesis of manganese(iii)-peroxo (Mn (O )) and manganese(iii)-hydroperoxo (Mn (O H)) complexes by activating dioxygen (O ) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc09492b