Iron-Catalyzed Aerobic Oxidation and Annulation Reaction of Pyridine and α‑Substituted Allenoate toward Functionalized Indolizine

Iron-Catalyzed Aerobic Oxidation and Annulation Reaction of Pyridine and α‑Substituted Allenoate toward Functionalized Indolizine

An iron-catalyzed reaction of pyridine and α-substituted allenoate has been disclosed. The present strategy incorporates the aerobic oxidation into annulation involving substituted allenoate, thus providing a new access to functionalized indolizine.

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Veröffentlicht in:Organic letters 2018-01, Vol.20 (2), p.413-416
Hauptverfasser: Jin, Tao, Tang, Zhongzhong, Hu, Jie, Yuan, Hongdong, Chen, Yaoyao, Li, Chunju, Jia, Xueshun, Li, Jian
Format: Artikel
Sprache:eng
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Zusammenfassung:An iron-catalyzed reaction of pyridine and α-substituted allenoate has been disclosed. The present strategy incorporates the aerobic oxidation into annulation involving substituted allenoate, thus providing a new access to functionalized indolizine.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b03696