Poly(ethylene glycol)–[60]Fullerene‐Based Materials for Perovskite Solar Cells with Improved Moisture Resistance and Reduced Hysteresis

A series of [60]fullerenes covalently functionalized with the polymer poly(ethylene glycol) is presented. These new [60]fullerene‐based materials have been incorporated as additives in CH3NH3PbI3 (MAPbI3), the most common organic–inorganic perovskite used in perovskite solar cells. The extensive photovoltaic study performed by using these materials shows several beneficial effects on the performance of these cells, including a reduction in hysteresis and an increased stability against moisture, whereby the solar cells retain up to 97 % of their initial power conversion efficiency in an ambient atmosphere. Solar cells off the PEG: A series of [60]fullerenes covalently functionalized with poly(ethylene glycol) is presented. These materials have been incorporated as additives in CH3NH3PbI3, which is the most common hybrid perovskite used in solar cells. The extensive photovoltaic study performed with these materials indicates beneficial effects including reduced hysteresis and increased stability against moisture.