Fe(II)/Fe(III)-Catalyzed Intramolecular Didehydro-Diels–Alder Reaction of Styrene-ynes

The intramolecular didehydro-Diels–Alder reaction of styrene-ynes was catalyzed by Fe­(II) and Fe­(III) to produce various naphthalene derivatives under microwave heating conditions. Mechanistic calculations found that the Fe­(II) catalyst activates the styrenyl diene in an inverse-electron-demand Diels–Alder reaction, and the consecutive dehydrogenation reaction can be promoted by either Fe­(II)-catalyzed direct dehydrogenation or an Fe­(III)-catalyzed rearomatization/dehydrogenation pathway.