Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopants

Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopants

Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l in CHCl ) and acts as an efficient p-dopant for poly(3...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (3), p.307-310
Hauptverfasser: Karpov, Y, Kiriy, N, Al-Hussein, M, Hambsch, M, Beryozkina, T, Bakulev, V, Mannsfeld, S C B, Voit, B, Kiriy, A
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Dopants
Inorganic salts
Thermal stability
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Beschreibung
Zusammenfassung:Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l in CHCl ) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm .
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc08671g