Acid-catalyzed reaction of 2-hydroxycyclobutanone with benzylic alcohols

The acid-promoted syntheses of 2-(benzyloxy)cyclobutanones and bis(benzyloxy)dioxatricyclo decanes were achieved starting from 2-hydroxycyclobutanone and variously functionalized benzyl alcohols. The reaction sequences afforded the desired products in good to high yields and in a solvent-dependent c...

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Veröffentlicht in:	Organic & biomolecular chemistry 2017, Vol.15 (47), p.10053-10063
Hauptverfasser:	Martis, Alberto, Luridiana, Alberto, Frongia, Angelo, Arca, Massimiliano, Sarais, Giorgia, Aitken, David J, Guillot, Regis, Secci, Francesco
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Alcohol Alcohols Benzyl alcohol
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The acid-promoted syntheses of 2-(benzyloxy)cyclobutanones and bis(benzyloxy)dioxatricyclo decanes were achieved starting from 2-hydroxycyclobutanone and variously functionalized benzyl alcohols. The reaction sequences afforded the desired products in good to high yields and in a solvent-dependent chemoselective fashion.
ISSN:	1477-0520 1477-0539
DOI:	10.1039/c7ob02545a