Thermolysis of scrap tire and rubber in sub/super-critical water

[Display omitted] •Temperature-pressure independent-adjustable reactor was newly designed.•Thermolysis of waste tire in sub/super-critical was performed.•The compounds of pyrolytic oil were mainly low molecular alkanes.•The combustible gas of pyrolytic gases were CH4, C2H2, C2H4, C2H6 and C3H8.•The optimal operational conditions were recommended. The rapid growth of waste tires has become a serious environmental issue. Energy and material recovery is regarded as a promising use for waste tires. Thermolysis of scrap tire (ST), natural rubber (NR), and styrene-butadiene rubber (SBR) was carried out in subcritical and supercritical water using a temperature-pressure independent adjustable batch tubular reactor. As a result, oil yields increased as temperature and pressure increased, and they reached maximum values as the state of water was near the critical point. However, further increases in water temperature and pressure reduced the oil yields. The maximum oil yield of 21.21% was obtained at 420 °C and 18 MPa with a reaction time of 40 min. The relative molecular weights of the chemicals in the oil products were in the range of 70–140 g/mole. The oil produced from ST, NR, and SBR contained similar chemical compounds, but the oil yield of SR was between those of NR and SBR. The oil yield from thermolysis of subcritical or supercritical water should be further improved. The main gaseous products, including CH4, C2H2, C2H4, C2H6, and C3H8, increased with reaction time, temperature, and pressure, whereas the solid residues, including carbon black and impurities, decreased. These results provide useful information to develop a sub/super-critical water thermolysis process for energy and material regeneration from waste tires.