Recent Progress in the Surface Modification of Photoelectrodes toward Efficient and Stable Overall Water Splitting

Photoelectrochemical (PEC) water splitting using a combination of a photocathode and photoanode is one of the most promising methods of producing hydrogen from water employing sunlight. Recent reports have shown that surface modification of the photoelectrodes dramatically improves their PEC performance. Bare photoelectrodes often exhibit insufficient depletion regions, undesired surface states and/or degradation due to photocorrosion. It has been demonstrated that surface modifications can tune the flat‐band potentials, band‐edge potentials, surface states and chemical stabilities of these electrodes and thus improve quantum efficiency, onset potential and durability. This review describes in detail the various surface modification materials that have been developed to date, and the functions of these modifiers. This information is expected to provide guidelines for the future development of photoelectrodes capable of highly efficient and stable PEC water splitting. Surface modification of photoelectrodes for water splitting improves their photoelectrochemical properties dramatically. A surface‐modified photoelectrode shows enhanced charge separation and stability compared with the bare photoelectrode. In this Minireview, the functions and materials of surface modifiers recently reported are highlighted.