Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N‑Sulfonylbenzamides

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N‑Sulfonylbenzamides

Hydroxoiridium complexes efficiently catalyzed the hydroarylation of alkynes and bicycloalkenes with N-sulfonylbenzamides via C–H activation to give the corresponding ortho-alkenylation and alkylation products in high yields.

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Veröffentlicht in:Organic letters 2017-11, Vol.19 (21), p.5952-5955
Hauptverfasser: Nagamoto, Midori, Fukuda, Jun-ichi, Hatano, Miyuki, Yorimitsu, Hideki, Nishimura, Takahiro
Format: Artikel
Sprache:eng
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Zusammenfassung:Hydroxoiridium complexes efficiently catalyzed the hydroarylation of alkynes and bicycloalkenes with N-sulfonylbenzamides via C–H activation to give the corresponding ortho-alkenylation and alkylation products in high yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.7b02950