Discoloration process modeling by neural network

The photo-oxidation of acid orange 52 dye was performed in the presence of H 2O 2, utilizing UV light, aiming the discoloration process modeling and the process variable influence characterization. The discoloration process was modeled by the use of feedforward neural network. Each sample was charac...

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Veröffentlicht in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2008-07, Vol.140 (1), p.71-76
Hauptverfasser: Guimarães, Oswaldo Luiz Cobra, Chagas, Marta Heloisa dos Reis, Filho, Darcy Nunes Villela, Siqueira, Adriano Francisco, Filho, Hélcio José Izário, Aquino, Henrique Otávio Queiroz de, Silva, Messias Borges
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Sprache:eng
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Zusammenfassung:The photo-oxidation of acid orange 52 dye was performed in the presence of H 2O 2, utilizing UV light, aiming the discoloration process modeling and the process variable influence characterization. The discoloration process was modeled by the use of feedforward neural network. Each sample was characterized by five independent variables (dye concentration, pH, hydrogen peroxide volume, temperature and time of operation) and a dependent variable (absorbance). The neural model has also provided, through Garson Partition coefficients and the Pertubation method, the independent variable influence order determination. The results indicated that the time of operation was the predominant variable and reaction mean temperature was the lesser influent variable. The neural model obtained presented coefficients of correlation on the order 0.98, for sets of trainability, validation and testing, indicating the power of prediction of the model and its character of generalization.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2007.09.021