Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic AuAu interactions

Cooperative self-assembly and gelation of organogold(i) complexes via hydrogen bonding and aurophilic AuAu interactions

With the synergistic combination of intermolecular Au(i)-Au(i) and hydrogen bonding interactions, a rod-coil alkynyl-gold(i)-isocyanide monomer tends to form supramolecular fibers and gels via a cooperative nucleation-elongation self-assembly mechanism, which display Ag(i) ion-triggered responsivene...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (84), p.11552-11555
Hauptverfasser: Chen, Jiangjun, Zhang, Zhongxin, Wang, Chengming, Gao, Zhao, Gao, Zongchun, Wang, Feng
Format: Artikel
Sprache:eng
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Zusammenfassung:With the synergistic combination of intermolecular Au(i)-Au(i) and hydrogen bonding interactions, a rod-coil alkynyl-gold(i)-isocyanide monomer tends to form supramolecular fibers and gels via a cooperative nucleation-elongation self-assembly mechanism, which display Ag(i) ion-triggered responsiveness.
ISSN:1364-548X
DOI:10.1039/c7cc05613c