Metal‐Based Diversity for Crystalline Metal‐Fullerene Frameworks

Metal‐Based Diversity for Crystalline Metal‐Fullerene Frameworks

Four different three‐dimensional metal–fullerene frameworks were synthesized through polymerization of two C60‐derived dodecaacids with varying alkyl spacers in the presence of Ca2+, Cu2+ or Cd2+ ions. Structural analysis of the frameworks was performed by single‐crystal X‐ray diffraction and porosi...

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Veröffentlicht in:Chemistry : a European journal 2017-11, Vol.23 (63), p.15864-15868
Hauptverfasser: Kraft, Andreas, Roger, Chantal, Schmidt, David, Stangl, Johannes, Müller‐Buschbaum, Klaus, Beuerle, Florian
Format: Artikel
Sprache:eng
Schlagworte:
Buckminsterfullerene
Cadmium
Calcium
Chemical synthesis
Chemistry
Copper
Crystal structure
Crystals
Diffraction
Fullerenes
metal-organic frameworks
Metals
Polymerization
Porosity
Single crystals
Structural analysis
X-ray diffraction
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Beschreibung
Zusammenfassung:Four different three‐dimensional metal–fullerene frameworks were synthesized through polymerization of two C60‐derived dodecaacids with varying alkyl spacers in the presence of Ca2+, Cu2+ or Cd2+ ions. Structural analysis of the frameworks was performed by single‐crystal X‐ray diffraction and porosity of the materials was investigated by sorption measurements. The metal makes the difference: Structural variety was obtained for metal‐fullerene frameworks through metal‐organic polymerization of [60]fullerene dodecaacids with different metal salts.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201703709