Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives

Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives

Modification of GO by organic molecules changes its catalytic activity in the hydrogen transfer from i-propanol to enones, affecting the selectivity to allyl alcohol and diastereoselectivity to the resulting stereoisomers. It is noteworthy the system does not contain metals and is recyclable.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-09, Vol.53 (74), p.10271-10274
Hauptverfasser: Coman, Simona M, Podolean, Iunia, Tudorache, Madalina, Cojocaru, Bogdan, Parvulescu, Vasile I, Puche, Marta, Garcia, Hermenegildo
Format: Artikel
Sprache:eng
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Zusammenfassung:Modification of GO by organic molecules changes its catalytic activity in the hydrogen transfer from i-propanol to enones, affecting the selectivity to allyl alcohol and diastereoselectivity to the resulting stereoisomers. It is noteworthy the system does not contain metals and is recyclable.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc05105k