Ring expansion of a ring expanded carbene

Ring expansion of a ring expanded carbene

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-09, Vol.46 (36), p.12015-12018
Hauptverfasser: García, Lucía, Al Furaiji, Khalidah H M, Wilson, David J D, Dutton, Jason L, Hill, Michael S, Mahon, Mary F
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt03046k