Vertical profile of peroxyacetyl nitrate (PAN) from MIPAS-STR measurements over Brazil in February 2005 and its contribution to tropical UT NO sub(y) partitioning

We report on the retrieval of PAN (CH sub(3)C(O)OONO sub(2)) in the upper tropical troposphere from limb measurements by the remote-sensor MIPAS-STR on board the Russian high altitude research aircraft M55-Geophysica. The measurements were performed close to Aracaatuba, Brazil, on 17 February 2005. The retrieval was made in the spectral range 775-820 cm super(-1) where PAN exhibits its strongest feature but also more than 10 species interfere. Especially trace gases such as CH sub(3)CCl sub(3), CFC-113, CFC-11, and CFC-22, emitting also in spectrally broad not-resolved branches, make the processing of PAN prone to errors. Therefore, the selection of appropriate spectral windows, the separate retrieval of several interfering species and the careful handling of the water vapour profile are part of the study presented. The retrieved profile of PAN has a maximum of about 0.14 ppbv at 10 km altitude, slightly larger than the lowest reported values (