Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation
Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
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| Veröffentlicht in: | Journal of the American Chemical Society 2017-09, Vol.139 (36), p.12386-12389 |
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| container_end_page | 12389 |
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| container_issue | 36 |
| container_start_page | 12386 |
| container_title | Journal of the American Chemical Society |
| container_volume | 139 |
| creator | Harper, Matthew J Emmett, Edward J Bower, John F Russell, Christopher A |
| description | Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical. |
| doi_str_mv | 10.1021/jacs.7b06668 |
| format | Article |
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| title | Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation |
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