Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation

Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.

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Veröffentlicht in:Journal of the American Chemical Society 2017-09, Vol.139 (36), p.12386-12389
Hauptverfasser: Harper, Matthew J, Emmett, Edward J, Bower, John F, Russell, Christopher A
Format: Artikel
Sprache:eng
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Zusammenfassung:Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.7b06668