A novel synthesis of an Fe3+/Fe2+ layered double hydroxide ('green rust') via controlled electron transfer with a conducting polymer

A novel synthesis of an Fe3+/Fe2+ layered double hydroxide ('green rust') via controlled electron transfer with a conducting polymer

This report examines the influence of a conducting polymer on the crystal growth of labile green rust (GR) through hybridization with polypyrrole. All hybrids used in this study were prepared via one-pot co-precipitation at neutral pH, with specific stoichiometric ratios among all chemical species....

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-06, Vol.46 (24), p.7656-7659
Hauptverfasser: Kim, Min-Sung, Kim, Tae-Hyun, Seo, Young Sun, Oh, Jae-Min, Park, Jin Kuen
Format: Artikel
Sprache:eng
Schlagworte:
Conducting polymers
Coprecipitation
Crystal growth
Electron transfer
Green rust
Hydroxides
Polypyrroles
Synthesis (chemistry)
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Beschreibung
Zusammenfassung:This report examines the influence of a conducting polymer on the crystal growth of labile green rust (GR) through hybridization with polypyrrole. All hybrids used in this study were prepared via one-pot co-precipitation at neutral pH, with specific stoichiometric ratios among all chemical species. The role of the conducting polymer and the effective stoichiometric ratio were demonstrated to facilitate the crystal growth of GR.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00731k