Room temperature silylation of alcohols catalyzed by metal organic frameworks

Room temperature silylation of alcohols catalyzed by metal organic frameworks

The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction condition...

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Veröffentlicht in:Catalysis science & technology 2017, Vol.7 (12), p.2445-2449
Hauptverfasser: Dhakshinamoorthy, Amarajothi, Santiago-Portillo, Andrea, Concepción, Patricia, Herance, José R., Navalón, Sergio, Alvaro, Mercedes, Garcia, Hermenegildo
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Aliphatic alcohols
Catalysis
Catalysts
Metal-organic frameworks
Toluene
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Zusammenfassung:The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction conditions as evidenced by powder XRD and can be reused with minimal activity decrease.
ISSN:2044-4753
2044-4761
DOI:10.1039/C7CY00834A