Mechanochemical synthesis of two-dimensional aromatic polyamides

Mechanochemical synthesis of two-dimensional aromatic polyamides

Herein we report a facile mechanochemical synthesis of 2D aromatic polyamides (2DAPAs) under solvent-free and room temperature conditions for the first time. The solvent-free conditions are found to be key to the successful synthesis of 2DAPAs. These micrometer-size 2DAPAs have ultrathin graphene-li...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (54), p.7481-7484
Hauptverfasser: Yang, Yang, Bu, Fanxing, Liu, Jingjing, Shakir, Imran, Xu, Yuxi
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic polyamides
Crystal structure
Dispersion
Mechanochemistry
Solvents
Synthesis
Thermal stability
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Zusammenfassung:Herein we report a facile mechanochemical synthesis of 2D aromatic polyamides (2DAPAs) under solvent-free and room temperature conditions for the first time. The solvent-free conditions are found to be key to the successful synthesis of 2DAPAs. These micrometer-size 2DAPAs have ultrathin graphene-like structures and are highly crystalline, solvent dispersible and thermally stable up to 400 °C.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02648j